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AN10079809-20000930-0021.pdf
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Download
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:961.0 KB
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| Last updated |
:Apr 27, 2007 |
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Total downloads since Apr 27, 2007 : 2202
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| Title |
| Title |
トリシクロ［9.3.0.0 4,8］テトラデカン-2,9-ジオン類およびトリシクロ［9.3.0.0 3,7］テトラデカン-2,9-ジオンのグリニヤ反応によるメチル化
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| Kana |
トリシクロ ［9.3.0.0 4,8］ テトラデカン-2,9-ジオンルイ オヨビ トリシクロ ［9.3.0.0 3,7］ テトラデカン-2,9-ジオン ノ グリニヤ ハンノウ ニヨル メチルカ
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| Romanization |
Torishikuro ［9.3.0.0 4,8］ tetoradekan 2,9-jionrui oyobi torishikuro ［9.3.0.0 3,7］ tetoradekan-2,9-jion no guriniya hanno niyoru mechiruka
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| Other Title |
| Title |
The methylation of Tricyclo［9.3.0.0 4,8］tetradecance-2,9-diones and Tricyclo［9.3.0.0 3,7］tetradecane-2,9-dione by grignard reaction
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| Creator |
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梅原, 美佐緒
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ウメハラ, ミサオ
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Umehara,Misao
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| Affiliation |
慶応義塾大学化学教室
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Department of Chemistry，Keio University
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大場, 茂
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オオバ, シゲル
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| Romanization |
Ohba, Shigeru
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| Affiliation |
慶応義塾大学理工学部
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| Affiliation (Translated) |
Department of Chemistry，Faculty of Science andTechnology， Keio University
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山崎, 貴弘
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ヤマザキ, タカヒロ
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Yamazaki, Takahiro
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| Affiliation |
化学学科
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| Affiliation (Translated) |
Department of Chemistry，Keio University
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| Affiliation |
慶応義塾大学化学教室
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慶應義塾大学日吉紀要刊行委員会
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| Kana |
ケイオウ ギジュク ダイガク ヒヨシ キヨウ カンコウ イインカイ
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| Romanization |
Keio gijuku daigaku hiyoshi kiyo kanko iinkai
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| Issued (from:yyyy) |
2000
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慶應義塾大学日吉紀要. 自然科学
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28
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2000
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9
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| Start page |
21
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38
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| Abstract |
Several isomers of CS-CB-CS fused ring compounds， tricyclo[9.3.0.0]tetradecane-2，9-diones and tricyclo[9.3.0.0]tetradecane-2，9-dione weremethylated by Grignard reagent. In these cis/trans isomers of ring junctions， thereaction products were differed respectively， resulting from transannular effectand difference in conformations of the eight-membered rings. Heat of formationsand steric energies of these reaction products were evaluated by semi-empiricalquantum mechanics(MOPAC/AM1)and moleculor mechanics(MM2)， whichare consistent with the experimental results. The molecular structures of twomono-methylated compounds were determined by X-ray crystallography.
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| Departmental Bulletin Paper
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