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KO50001004-00260005-0055.pdf
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Title |
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Bonding nature and semiconductivity of coordination polymers of the type KM[Fe(CN)6]
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井上, 秀成
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Kana |
イノウエ, ヒデナリ
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Romanization |
Inoue, Hidenari
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Affiliation |
Dept. of Applied Chemistry, Keio University
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柳沢, 三郎
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ヤナギサワ, サブロウ
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Romanization |
Yanagisawa, Saburo
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Affiliation |
Dept. of Applied Chemistry, Keio University
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慶応義塾大学工学部
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ケイオウ ギジュク ダイガク コウガクブ
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Romanization |
Keio gijuku daigaku kogakubu
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Issued (from:yyyy) |
1973
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Keio engineering reports
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26
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5
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1973
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Start page |
55
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66
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Abstract |
A series of coordination polymers of the type KM[Fe(CN)6] (M=Mn, Fe, Co, Ni, Cu or Zn) have the face-centered cubic unit cell characteristic of Prussian blue analogs. The lattice parameter and magnetic susceptibility data have indicated that these compounds consist of carbon-coordinated low-spin Fe(III) ion and nitrogen-coordinated high-spin M(II) ion. The C≡N stretching, Fe-C stretching and Fe-CN bending frequencies are shifted to the higher frequency side compared with those of corresponding potassium hexacyanoferrates. This shift provides an evidence for the existence of the linkage structure Fe-C≡N-M. The conductivity-temperature curves have the characteristics of semiconductor in the range from room temperature to about 170℃. This property could be interpreted in terms of weak metal-metal interaction through the bridged cyanide group.
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Departmental Bulletin Paper
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