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KAKEN_17K19131seika.pdf
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Download
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:232.2 KB
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| Last updated |
:Oct 31, 2019 |
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Total downloads since Oct 31, 2019 : 442
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| Title |
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ジグザグ型ヘテロカーボンナノベルトの合成
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| Kana |
ジグザグガタ ヘテロカーボン ナノベルト ノ ゴウセイ
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Jiguzagugata heterokābon nanoberuto no gōsei
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Synthesis of zig-zag type heterocarbon nanobelt
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東林, 修平
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ヒガシバヤシ, シュウヘイ
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Higashibayashi, Shūhei
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| Affiliation |
慶應義塾大学・薬学部 (芝共立)・准教授
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Research team head
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科研費研究者番号 : 30338264
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2019
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科学研究費補助金研究成果報告書
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2018
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カルバゾール、ジベンゾフラン、フェノチアジンの臭素化体のニッケル(0)によるカップリングによって、環型、おわん型、フレーク型、らせん型の三次元構造を有する新たな分子の合成に成功した。合成した分子は、蛍光、酸化還元などにおいて優れた物性を示すことを明らかにし、その特性を利用して、蛍光物質、リチウム有機二次電池の活物質、蛍光バイオイメージングに応用することに成功した。
Three-dimensional ring-, bowl-, flake-, and helix-shaped molecules were successfully synthesized by N(0)-mediated coupling of bromo derivatives of carbazole, dibenzofuran, and phenothiazine. These synthesized molecules were found to show excellent properties such fluorescence and redox. They were successfully applied to fluorescence materials, active materials of rechargeable lithium organic battery, and fluorescence bio-imaging.
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研究種目 : 挑戦的研究(萌芽)
研究期間 : 2017～2018
課題番号 : 17K19131
研究分野 : 有機合成化学, 構造有機化学, 天然物化学
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